| Pick # | Date | |
| Grand Duchy | ||
| 1 | 1856-94 | 10 Thaler |
| 1-3 | 1856-94 | 25, 100 francs |
| 4-5 | 1900 | 20, 50 mark |
| 6-8 | 1914 | 1, 2, 5 mark |
| 9-11 | 1923-40 | 100 francs |
| 12 | 1947 | 100 francs |
| 13 | 1956 | 100 francs |
| 14 | 1968 | 100 francs |
| 14A | 1981 | 100 francs |
| 15-17 | 1873 | 5, 10, 20 Thaler |
| 17A-17B | 1873 | 20, 100 francs |
| 18-20 | 1876 | 5, 10, 20 mark |
| 21-25 | 1914 | 1, 2, 5, 5, 25, 125 francs |
| 26-33 | 1918 | 50 Cenimes, 1, 2, 5, 5, 25, 125, 500 francs |
| 34-36 | (192-) | 10, 20, 100 francs |
| 37-40 | 1929-39 | 20, 50, 100, 1.000 francs |
| 42 | 1943 | 20 francs |
| 43-47 | (1944) | 5, 10, 50, 50, 100 francs |
| 48-50 | (195-) | 10, 20, 100 francs |
| 51-52 | 1961-63 | 50, 100 francs |
| 53-56 | 1966-72 | 10, 20, 50, 100 francs |
| 57 | 1980 | 100 francs |
| 58-59 | (1985) | 100, 1.000 francs |
| 60 | (1993),1996 | 5.000 francs |